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</div> </li> <li> <a href="/ParentList-1936176.html" title="螯合樹(shù)脂" onmouseover="showsubmenu('螯合樹(shù)脂')">螯合樹(shù)脂</a> <div class="jd91ldt" id="submenu_螯合樹(shù)脂" style="display:none"> <ul class="two_profl"> </ul> </div> </li> <li> <a href="/ParentList-1936177.html" title="鍋爐軟化水樹(shù)脂" onmouseover="showsubmenu('鍋爐軟化水樹(shù)脂')">鍋爐軟化水樹(shù)脂</a> <div class="tb9vrpn" id="submenu_鍋爐軟化水樹(shù)脂" style="display:none"> <ul class="two_profl"> <li><a href="/SonList-1946854.html" title="軟化水樹(shù)脂">軟化水樹(shù)脂</a></li> <li><a href="/SonList-1946852.html" title="鍋爐軟化水樹(shù)脂">鍋爐軟化水樹(shù)脂</a></li> </ul> </div> </li> </ul> </div> </div> <div id="vfp5d5p" class="nymiddlezty"> <div id="ntl95hn" class="mianbao">您現在的位置：<a href="/">首頁(yè)</a> >> <a href="/article.html">技術(shù)文章</a> >> 732陽(yáng)離子交換樹(shù)脂</div> <div id="lv9ltxl" class="about_con"> <div id="pz9zl9x" class="newstit">732陽(yáng)離子交換樹(shù)脂</div> <div id="j5pnfbn" class="newstime"> <span id="ndzfxz5" class="skim"><em>瀏覽次數：</em>1648</span><span id="tbrxtvf" class="skimtim"><em>發(fā)布日期：</em>2020-05-30 </span> </div> <p>732陽(yáng)離子交換樹(shù)脂<br />732陽(yáng)離子交換樹(shù)脂?！纠确换ぁ课夜緭碛幸恢в蓪?zhuān)家、教授組成的專(zhuān)業(yè)科研隊伍，以大專(zhuān)院?？萍汲晒麨榧夹g(shù)依托，憑借雄厚的實(shí)力、的生產(chǎn)設備、的檢測手段、科學(xué)嚴謹的管理，產(chǎn)品達到國家標準、電力標準、石化標準。廣泛應用于冶金、電力、化工、石油、造紙、醫藥、船舶和汽車(chē)制造等行業(yè)。<br />弱酸性陽(yáng)離子樹(shù)脂<br />這類(lèi)樹(shù)脂含弱酸性基團，如羧基-COOH，能在水中離解出H+而呈酸性。樹(shù)脂離解后余下的負電基團，如R-COO-(R為碳氫基團)，能與溶液中的其他陽(yáng)離子吸附結合，從而產(chǎn)生陽(yáng)離子交換作用。這種樹(shù)脂的酸性即離解性較弱，在低pH下難以離解和進(jìn)行離子交換，只能在堿性、中性或微酸性溶液中(如pH5～14)起作用。這類(lèi)樹(shù)脂亦是用酸進(jìn)行再生(比強酸性樹(shù)脂較易再生)。<br />強堿性陰離子樹(shù)脂<br />這類(lèi)樹(shù)脂含有強堿性基團，如季胺基(亦稱(chēng)四級胺基)-NR3OH(R為碳氫基團)，能在水中離解出OH-而呈強堿性。這種樹(shù)脂的正電基團能與溶液中的陰離子吸附結合，從而產(chǎn)生陰離子交換作用。<br />這種樹(shù)脂的離解性很強，在不同pH下都能正常工作。它用強堿(如NaOH)進(jìn)行再生。<br />這兩類(lèi)樹(shù)脂的吸附性能都很好，但有不同特點(diǎn)。丙烯酸系樹(shù)脂能交換吸附大多數離子型色素，脫色容量大，而且吸附物較易洗脫，便于再生，在糖廠(chǎng)中可用作主要的脫色樹(shù)脂。苯乙烯系樹(shù)脂擅長(cháng)吸附芳香族物質(zhì)，善于吸附糖汁中的多酚類(lèi)色素(包括帶負電的或不帶電的)；但在再生時(shí)較難洗脫。因此，糖液先用丙烯酸樹(shù)脂進(jìn)行粗脫色，再用苯乙烯樹(shù)脂進(jìn)行精脫色，可充分發(fā)揮兩者的長(cháng)處。<br />樹(shù)脂的交聯(lián)度，即樹(shù)脂基體聚合時(shí)所用二乙烯苯的百分數，對樹(shù)脂的性質(zhì)有很大影響。通常，交聯(lián)度高的樹(shù)脂聚合得比較緊密，堅牢而耐用，密度較高，內部空隙較少，對離子的選擇性較強；而交聯(lián)度低的樹(shù)脂孔隙較大，脫色能力較強，反應速度較快，但在工作時(shí)的膨脹性較大，機械強度稍低，比較脆而易碎。工業(yè)應用的離子樹(shù)脂的交聯(lián)度一般不低于4；用于脫色的樹(shù)脂的交聯(lián)度一般不高于8；單純用于吸附無(wú)機離子的樹(shù)脂，其交聯(lián)度可較高。<br />既然是一種離子交換樹(shù)脂，那么它的作用環(huán)境就是溶液。水溶液中一般還有的是金屬陽(yáng)離子，這些金屬陽(yáng)離子可以與材料上的氫離子發(fā)生離子交換作用，這樣溶液中的陽(yáng)離子就會(huì )跑到材料上，這樣陽(yáng)離子就交換完畢。這個(gè)過(guò)程靠的就是離子交換樹(shù)脂的原料的作用。<br />而陰離子的交換和上面的是一樣的，就是水中的陰離子與材料上的OH-交換，交換到水中的H+與OH-反應生成水，這樣就會(huì )使溶液脫鹽。我們生產(chǎn)廠(chǎng)家在多年的生產(chǎn)中，提高了離子交換樹(shù)脂壽命，讓人們從一定程度上節約了成本。<br />離子交換樹(shù)脂的定義就是脫鹽，是溶液中的鹽分脫離出來(lái)。離子交換樹(shù)脂的工作原理是及其簡(jiǎn)單的，廠(chǎng)家關(guān)鍵是選擇良好的材料才能將這種原理體現出來(lái)。如果你需要這種產(chǎn)品，可以到我們廠(chǎng)家進(jìn)行挑選，保證使用方便，使用時(shí)間長(cháng)。<br />通常，交聯(lián)度高的樹(shù)脂對離子的選擇性較強，大孔結構樹(shù)脂的選擇性小于凝膠型樹(shù)脂。這種選擇性在稀溶液中較大，在濃溶液中較小。<br />大孔型樹(shù)脂是在聚合反應時(shí)加入致孔劑，形成多孔海綿狀構造的骨架，內部有大量性的微孔，再導入交換基團制成。它并存有微細孔和大網(wǎng)孔(macro-pore)，潤濕樹(shù)脂的孔徑達100～500nm，其大小和數量都可以在制造時(shí)控制?？椎赖谋砻娣e可以增大到超過(guò)1000m2/g。這不僅為離子交換提供了良好的接觸條件，縮短了離子擴散的路程，還增加了許多鏈節活性中心，通過(guò)分子間的范德華引力(vandeWaalsforce)產(chǎn)生分子吸附作用，能夠象活性炭那樣吸附各種非離子性物質(zhì)，擴大它的功能。一些不帶交換功能團的大孔型樹(shù)脂也能夠吸附、分離多種物質(zhì)，例如化工廠(chǎng)廢水中的酚類(lèi)物。<br />大孔陽(yáng)離子的分類(lèi)有哪些呢？<br />D001<br />大孔強酸性苯乙烯系陽(yáng)離子交換樹(shù)脂<br />高純水處理、二級除鹽混床、有機物含量高的水及機反應催化劑等。硬水軟化和純水制備，工業(yè)廢水處理，貴金屬的回收處理，及作為酸性觸媒。<br />D201<br />大孔強堿性苯乙烯系陰離子交換樹(shù)脂<br />高要用于高速混床凝結水處理裝置、廢水處理、重金屬回收。<br /><br />732陽(yáng)離子交換樹(shù)脂<br />濃度差越大，交換速度越快。離子交換樹(shù)脂對不同離子具有不同的吸附性能。這種選擇性與樹(shù)脂本身的官能團、骨架結構和交聯(lián)程度有關(guān)，也與溶液中離子的濃度和價(jià)態(tài)有關(guān)。一般來(lái)說(shuō)，離子價(jià)越高，靜電對樹(shù)脂官能團的吸引力越大，親和力也越大；共價(jià)離子的原子數目越多，樹(shù)脂對樹(shù)脂的選擇性也越高。由于陽(yáng)離子交換劑可以與水中的陽(yáng)離子交換，所以陽(yáng)離子交換劑可以與水中的陰離子交換。因此，通過(guò)選擇合適的交換器，可以去除水中的所有雜質(zhì)離子，制得純水。用于制備純水的陽(yáng)離子交換樹(shù)脂是酸性的。主要交換基因為磺酸基、羧基或酚基，它們與水中的金屬離子以H+交換。陰離子交換樹(shù)脂是堿性的，其交換基團主要是季胺[-N(CH3)3OH]、伯胺(-NH2)等基本基因。</p> <div class="nbvbrdh" id="news_sx"><li id="hp5x5h5" class="sx_left">上一篇：<a href="/Article-2238294.html">201×7FC陰離子交換樹(shù)脂</a> <br />下一篇：<a href="/Article-2237731.html">D113FC陽(yáng)離子交換樹(shù)脂</a></li></div> </div> </div> </div> </div> <div id="9phjdlf" class="clear"></div> <div class="blvvbzt" id="footer"> <div id="9jvrd5p" class="footernr"> <div id="z5fdvbr" class="footersub1"> <p>工作時(shí)間</p> <span>為了避免不必要的等待，敬請注意我們的工作時(shí)間。以下是我們的正常工作時(shí)間，中國大陸法定節假日除外。</span><br> <span>工作時(shí)間：周一至周六早8:00-晚18:00。周日休息</span> </div> <div id="jvlhvfr" 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